Column: FIFA presidency no laughing matter as would-be candidate becomes frontman for gambling

10 will pit two Asian online bookmakers against each other. “There’s more passion, more pleasure and more pain.”

Ginola has zero chance of unseating Sepp Blatter. In pocketing 250,000 pounds (335,000 euros; US$375,000) from bookmaker Paddy Power for this stunt, Ginola became the latest Trojan horse in the gambling and gaming industry’s creeping and creepy embrace of football.

Sport “matters more when there’s money on it,” it says. What ever happened to sport for sport’s sake, for the buzz of competition, not a bet? How quaint. This was about making a splash. It reads like a plug for Fifty Shades of Grey.

That is the message that football, more than most other sports, is mainlining into our homes, helped by names like Ginola and teams lending their cachet, stadiums, jerseys and m88th players to the industry that had cash to splash when the 2008 financial crisis hobbled other sponsors.

But the targets were our wallets and spending habits, not our hearts. In the UK, which liberalized gambling advertising in 2007, adults’ exposure to gambling commercials on television soared five-fold in eight years to 2012, regulator Ofcom found. The increase was three-fold for children aged 4-15.

Sports and gambling have, of course, long gone together, feeding off each other’s success and growth. “It’s great for Paddy Power. But I mean you’re talking about one of the biggest, powerfulest jobs in football and all you’re getting to hear about is Paddy Power.”

Asking your kids to make tea during half-time breaks won’t shield them from the bombardment, not with gambling ads flashing throughout matches on pitch-side light-boards. Hull against Aston Villa on Feb. It won’t happen; FIFA’s ethics rules should see to that. Write to him at jleicester@ap.org or follow him at http://twitter.com/johnleicester

. Tuning in for results of football betting pools, which offered big jackpots for small stakes, was a Saturday afternoon ritual for many 20th Century English families.

We’re talking here about David Ginola. After Thursday’s passing of the entry deadline, “Team Ginola” should fade away.

Imagine, for a moment, a Paddy Power-financed FIFA president. FIFA’s election and ethics rules will almost certainly keep him off the May ballot. Bet some more.

John Leicester is an international sports columnist for The Associated Press.

And that isn’t funny at all.

Twaddle takes a very dim view of Ginola’s Paddy Power-backed grab for FIFA.

But that’s not the point here. But the mere thought of the gambling industry even attempting to place a stooge at the very top of football makes the prospect of another Blatter term seem perhaps not quite so bad.

“I’m here today to talk about love” were the Frenchman’s seductive opening words at his campaign launch in London this month.

“It’s eyeballs we’re after,” 12Bet executive Rory Anderson, quoted in the Daily Mail, said when the online bookmaker became the name on Hull City’s shirt for this Premier League season.

PARIS –  Don’t laugh. Bet again. So silky as a player for Newcastle and Tottenham; so ridiculous now with his car-crash campaign for the FIFA presidency.

And how about this blurb from Sky Bet, title sponsor since 2013 of England’s three divisions below the Premier League. There’s nothing funny about the gambling industry’s latest wheeze to sink its teeth even deeper into football and its fans.

Whoa. That much was clear from the Paddy Power branding.

“It’s an absolute disgrace,” he said in a phone interview. Villa’s shirt sponsor is dafabet, a name that works better in Chinese, where “dafa” means “big wealth.” Stoke and Burnley players are billboards for Bet365 and Fun88 (another name that plays on the Chinese word to get rich).

Bet. That was before online bookmakers offered odds on anything and everything, from match results and goals scored to which team will win the coin toss or take the first corner, and before their relentless advertising.

One of those is Kevin Twaddle, a former player for Motherwell and other Scottish clubs who told his story in the biography, “Life On The Line: How to Lose a Million and So Much More.” He no longer gambles and has delivered talks to other players about the risks.

___

All this in a sport grappling with the increasing danger of gambling-related match-fixing and with ample examples of gambling-addicted players who frittered away their wealth.

“It just makes like a mockery of football.”

But gambling advertising wasn’t as in-your-face as now

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Is Betting on Horses With Betting Exchanges a Sensible Thing to Do? Part Two by Cliff Thurston

Having secured your early price of 5/1, you place your bet of ?50 on the horse.. Therefore your total profit is ?150 less ?50, which is ?100.

However you are selecting your horses, betting with betting exchanges is certainly something that you should be doing.

Betting exchanges actually allow you to continue placing bets on horses in a race, even after the race has started. As you can see, there really is no mystique surrounding them and I highly recommend that you give them a go.

Well, it can and does happen. You may have a friend giving you racing tips on the sly (and for free) or you may be using some of the many horse racing systems that are out there.

By betting on horse racing using an exchange, this does not happen. You think the price will shorten come race time, and so you?ve done the right thing and taken the early price. It?s a tactic often used by traders who play the financial markets, but it can be used for betting on horse racing as well, and can guarantee you a profit on a given race.

Reason Four ? Trading Your Bets To Secure Yourself A Profit

However, if your horse loses it race, your lay bet will profit you ?150 (?75 at a price of 2/1) but your ?to win? ทางเข้า m88 bet was not successful and so you will pay out ?50 for this. More so in the local high street bookies, where you may be given the option to have some of the bet at 20/1 and some of the bet at the Starting Price ? which is likely to be far lower come race time.

Some of my members actually place their bets as soon as I advise them in the morning, meaning that they can take the best priced odds available, or indeed as I mentioned in the previous article, by naming their own price to see if it gets matched.

And when I use words like technical and detailed, you?ll be pleased to hear that I do not mean complicated. This is something that is both new and requires nerves of steel, as while the race is still going, the betting market for each horse is constantly changing as each horse jostles for position in the race.

Imagine that you?ve chosen to back a horse at 5/1 in a race. This enables you to take advantage of the often advantageous early prices of horses, long before everyone else starts lumping their cash on, leading to the price coming down.

Reason Two ? No Limit On Betting Stakes

I don?t know about you, but one of the real frustrations I have as a punter is reading the newspaper or hearing on the television of a good early price for a horse, yet when you go on the internet to check, prices are not always available.

Reason One ? Get Prices For Horses 24 Hours A Day

So this concludes part two, the final part of this article series regarding betting on horses using the betting exchanges. Due to the drop in price, you could also decide to lay the horse to lose and place ?75 on that bet.

In part one of this article series, I covered the basics about betting on horses with betting exchanges and showed why they have become so popular with punters.

I also went through three key reasons why you should use betting exchanges, whether you?re using a horse racing tipster service or backing your own judgment of the horses. So let?s crack on and look at these four key elements that could enable you to make more profit from horse racing.

I must admit that this is not something that I myself do, as it is simply too risky for my betting philosophy, however there are plenty that do like the excitement of it, and profit from it.

Guarantee a profit I hear you say, never. Well, let me explain:

Of course, in the longer races, say a two mile hurdle race, there is a little more time to think, but in a five furlong sprint race you do not have much time at all, in fact most races are over in 60 seconds or less!

And so in this article, I will explain some of the more technical and detailed facets of using a betting exchange, that could enable you to profit even more from your horse racing exploits.

How frustrated would you be if you?d received information from your horse racing tipster, about a gem of a horse that was over valued in price and likely to win its race, only to discover that putting a substantial bet on at 20/1 was out of the question?

And of course there is not a bookie in the land that opens there doors at 7am, so that avenue is blocked off as well.

If you?ve ever got to the bookies just as a race is about to start, only to be told by the ?friendly? assistant behind the desk that you?re too late to place your bet, then you?ll like this one.

Is Betting on Horses With Betting Exchanges a Sensible Thing to Do? Part Two

 by: Cliff Thurston

Reason Three ? The Race Has Started, But You Can Still Place Your Bet.

So there you have it, it is possible to guarantee that you make a profit in a race, if you are able to back the horse at one price and lay it at another (lower) price. As race time approaches, you notice that the price of your horse has come in from the 5/1 that you backed it at, to a price of 2/1. This can also be done in reverse too, so you could lay a horse to begin with, and if its price drifts out (increases) then you can guarantee profits by backing the horse at the higher price.

I?ve deliberately left this one until last, as it is a kind of an underground betting tactic if you like, although it is now growing in popularity. If you place a request to back a horse for a large sum at 20/1 and another punter is willing to lay the bet at that price, then you are able to have your bet placed without any questions being asked

If your horse wins its race, your winning bet will profit you ?250 (?50 at a price of 5/1) but your lay bet was not successful and so you will pay out ?75 for this. Therefore your total profit is ?250 less ?75, which is ?175.

So, how are you guaranteeing a profit by doing this? Well, there are of course only two possible outcomes for the horse that you?ve selected ?it will either win the race or it will not.

With a betting exchange however, you can place a bet whenever you want

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Zorobabel Moreira talks quickfire win over Christian Holley at ONE: ‘Dynasty of Champions’

There wasn’t any contact prior to that,” Moreira told MMAmania.com.

“It was a great experience to compete in China, it is the birthplace of martial arts and I really like the fans. I went back to Brazil for operation and it took me six months of physiotherapy and strength exercises to fully recover.”

“I’m not too sure what happened, to be honest. He was stopped by Kotetsu Boku and it would be two years before he stepped back inside the cage again, but the 32 year old says that contrary to earlier reports, this wasn’t a voluntary leave of absence.

. I worked every day at Evolve MMA with Muay Thai world champions Namsaknoi Yudthagarngamtorn and Nonthachai Sit-O and Heath Sims helped me with my wrestling and I was rolling every day with all the BJJ black belts.”

The matchup with Holley might not have tested Moreira’s cardio in quite the same way, but he believes he was ready to fight for the full 15 minutes if required.

Moreira is a decorated Brazilian Jiu-Jitsu (BJJ) black belt who surged to prominence as one of the earliest members of the Evolve MMA fight team. If they want me to fight Christian Holley again, I am happy to do that, I hope he can recover from his injury soon.”

Missing out on the inaugural ONE 155 lbs title was a blow to Moreira but he is happy to be back to winning ways. Every week I spend training at Evolve MMA I learn so much, I am always improving and I can’t wait to be back in the cage and show ONE FC fans all the new things I have learned.”

Moreira fought for the inaugural ONE Championship 155-pound title back in 2012.

“I am going back to Brazil for a month to see my family, but I am ready to fight again as soon as I get the call from ONE. It looks like Christian was already injured prior to the fight and he must have aggravated the injury when he threw his first kick towards me. After having spent the last seven years fighting in Singapore, Thailand, and Kuala Lumpur, this setting made a nice change for Zoro.

“My training camp was very good. He’s also proved extremely popular with Asian MMA fans and after getting his career back on track with a win, hopes to return to action again as soon as possible.

“I will never fight Shinya because he is my good friend and my team mate but I feel I have recovered from my injury now and my condition is good. The Brazilian was well ahead going into the third round, but rapidly ran out of energy and was stopped with less than a minute left in the fight.

“I suffered a torn ACL in training. It an accident to be honest, two big guys fell while grappling and they landed on my leg. The win took his record to 8-3 and was a first in three years, but the victory didn’t come in quitethe manner he might have imagined it,

In the contect of the two years he spent sidelined by injury, it’s understandable that Moreira struggled to stay the course in his comeback fight against Koji Ando. That belt is currently being worn by his Evolve MMA team mate Shinya Aoki but the Brazilian believes that time is still on his side,

ONE: “Dynasty of Champions” wasn’t broadcast live, so many fight fans will have been wondering exactly how Zorobabel Moreira managed to stop Christian Holley in 14 seconds flat. When I was walking to the cage, I could feel they had a big energy.”

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The card took place in Guangzhou and was ONE Championship’s second on Chinese soil

Quickfire goal from van Persie leaves Manchester Utd top of EPL

Story highlightsRobin van Persie scores after only 33 seconds for Manchester United 1-0 win over West Ham keeps them a point clear at top of EPLMario Balotelli scores as Manchester City beat Wigan 2-0 to stay second Chelsea held to second goalless draw under Rafael BenitezRobin van Persie scored after just 33 seconds as Manchester United maintained their slim advantage at the top of the English Premier League Wednesday with a 1-0 win over West Ham.

The Old Trafford faithful had barely settled in their seats when the Dutch striker picked up a pass from Michael Carrick and saw his shot deflect off James Collins to loop over visiting goalkeeper Jussi Jaaskelainen.

It was the quickest goal of the EPL season and left United a point clear of neighbors and defending champions Manchester City, who won 2-0 at Wigan.

United have fallen behind in many games this season before recovering and manager Alex Ferguson was delighted by their defensive display.

“If we can keep clean sheets more often than not it will a good foundation to challenge for the title,” he told Sky Sports.

Rafael Benitez is still searching for his first win and first goal since taking charge of Chelsea as interim manager following the sacking of Roberto Di Matteo.

Read: UEFA mulls Champions League expansion

His side were held 0-0 at home by West London rivals Fulham, off the back of the same result against Manchester City Sunday.

It left Chelsea seven points adrift of leaders Manchester United in third place in the standings and Benitez was again subjected to barracking by home supporters unhappy at his appointment.

West Bromwich Albion slipped back to fourth with a first defeat in five games, beaten 3-1 at Welsh side Swansea.

Spanish midfielder Michu scored his eighth EPL goal of the season to put Swansea ahead and they were two up inside 10 minutes when Wayne Routledge netted.

Routledge added his second and the home side’s third just before the interval, but there was still time for West Brom to pull one back when on-loan Romelu Lukaku scored in injury time at the end of the half.

Tottenham Hotspur took closer order in fifth with a 2-1 home win over Liverpool at White Hart Lane.

Aaron Lennon was set up by Gareth Bale for an early opener for Spurs. For me, he did not play very well,” he told Sky Sports.

Recalled Mario Balotelli gave City a second half lead at Wigan before James Milner sealed the three points with a thumping strike from outside the penalty area.

Balotelli’s performance earned scant praise from his manager Roberto Mancini.

“I think Mario can do better. Bale then put the home side two clear after just 16 minutes when he crashed home a deflected free kick.

In the second half, the pair were involved in a bizarre incident as Lennon smashed a clearance into Bale’s face and it found its way into the Tottenham goal, but Liverpool could not force an equalizer.

Everton and Arsenal are just behind them in sixth and seventh after they shared a 1-1 draw at Goodison Park.

Theo Walcott put the Gunners ahead in the first minute, but Belgian international Marouane Fellaini curled home a leveler midway through the first half.

Newcastle’s miserable recent run continued with a 2-1 defeat at Stoke while Southampton remained in the drop zone after a 1-1 draw at home to Norwich.

It was referee Mark Clattenburg’s first match in charge since being cleared of racially abusing Chelsea’s John Obi Mikel.

. He scored one important goal but can continue to improve

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by ban449 on January 13th, 2009

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one answer

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keithold is a prodigal bagger

In which country was the poker machine invented?

by keithold is a prodigal bagger on December 10th, 2008

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2 answers

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Player1234

Does anyone know the answers to the questions on www.howmanyticketsareleft.com?

by Player1234 on December 7th, 2008

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no answers

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Anonymous

Can you tell if a slott machine is going to pay out

by Anonymous on November 7th, 2008

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3 answers

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cactus

I just replaced the battery on a video poker game and get message cmos data, how can I get it to reset

by cactus on November 7th, 2008

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no answers

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Anonymous

If your where to hit a bonus on a slot machine is there a good chance you’ll get another bonus

by Anonymous on November 2nd, 2008

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4 answers

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Anonymous

If your where to hit a jackpot on a machine and cash out and put another 10 dollars in will it effect the pay rate

by Anonymous on November 1st, 2008

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3 answers

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hello

Where are the video poker machines in vegas that have the best odds?

by hello on October 9th, 2008

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one answer

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gtravels

I’m at Dover Downs Casino in Delaware right now. so i am not sure what to do thanks. Is there a way for me to reset the wheels to pay off correctly or do I find a manual.

by Stoney on September 11th, 2008

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questions

I recently played a slot machine in a casino and the machine went off flashing at the top saying I have won the jackpot,it also said so on the screen and all the correct winning icons were aligned,the cash amount was wrong,should I win t

by questions on September 11th, 2008

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. It does not pay off correctly.

catskinner

Hi i have a older slot machine and a friend of mine hit the jackpot on it but now i cant get it to reset the directions i got with it is not the write one and i can’t get a hold of the company i got it from. help

by blondie on September 14th, 2008

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no answers

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lecko

Looking for the name of a nickel reel slot machine that goes nuts when you hit the mania symbol and drops the bar symbol to the payout line if it has a ribbon in it? played in vegas last week

by lecko on September 13th, 2008

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no answers

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Stoney

I have a 25 cent 2 coin Black Cherry Slot Machine by IGT, I hit the jackpot and it paid 40 coins. She is taking out payday advances and borrowing money from him to support the habit. I hit the jackpot, 3 wild cherries and it gave me 40 coins. i just want to reset it and play. the 3300 is up

It’s not Thanksgiving without… – Eatocracy

If one of those dishes goes missing, the whole meal just doesn’t feel right.

- Actor Greg Grunberg says: his mother’s tamales

- The cast of ABC Family’s “Greek” says: showtunes and buckets of wishbones

- Megyn Price, start of ‘Rules of Engagement’ says: celery walnut salad.

Other families stray away from the standards – some friends of ours have to have collard greens, whiskey sours and banana pudding for the day to feel right, while another family dives into duck – and develop their own must-indulge traditions.

Your assignment – in video or pictures, and as much text as you’d like, using iReport, share the story of your must-have Thanksgiving dish. It could be a cherished family recipe, or something a schoolmate or fellow serviceman whipped up, and you simply must have on the table every year.

See the assignment on iReport and get caught up below.

It’s not Thanksgiving without…

We’ll share our favorites on Eatocracy from November 15-25, so start whipping ‘em up!

_Palaui_Island_Cagayan_Philippines.jpg” width=”336″ />

Even the most adventurous eaters often give their inner food warrior the day off on Thanksgiving – nothing but the same turkey, stuffing (or dressing!), cranberries, green bean casserole and pumpkin pie they’ve been eating since childhood

how much is the bus fare from davao to cagayan de oro for kinglong.?

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Deer invade thoroughbred track, canceling races

“No final resolution has been decided at this time,” Favre said Monday. This material may not be published, broadcast, rewritten, or redistributed. – A Pennsylvania thoroughbred track has canceled its racing card again as officials deal with deer running onto the track during races.

Sunday’s incident wasn’t the first involving deer, however, and jockeys said they’re becoming concerned. One deer ran onto the track at Presque Isle Downs Casino on Sunday, cutting in front of the lead horse during the fourth race. The union represents more than 1,300 retired and current U.S. “Management hasn’t done anything about the problem and it’s been going on for a week.”

© 2015 The Associated Press. All Rights Reserved. Five deer also interrupted the third race on June 22, prompting officials to cancel the final five races that day, track spokeswoman Jennifer See said.

“We’re taking this very seriously,” casino vice president and general manager Jeff Favre said. jockeys.

See, the track spokeswoman, didn’t immediately return a call for comment Tuesday about when racing will resume or whether any deer prevention measures have been approved.

Favre said the track may have officials walk along the track before races to keep deer away.

Officials also canceled racing cards for Monday and Tuesday while they looked for solutions.

“You can’t have animals weighing hundreds of pounds crossing in front of you when you’re going 35 to 40 miles an hour,” Rivera said. “It’s not as easy as one might think, and we’re working diligently to figure out what that long-term solution is.”. “The last thing we want is a jockey or horse to get hurt due to deer.”

“This is a very troubling situation,” said Heriberto Rivera, East Coast manager for the Jockey’s Guild. Four other races scheduled for that afternoon were canceled as a precaution, even though the deer didn’t collide with any horses, the Erie Times-News reported Tuesday.

ERIE, Pa

23 Quick Fire Music Marketing Tips

Ask for advice if you’re not sure.

Use #hashtags that are unique to you, and get your fans to post about you on social media using the same hashtags. Use Flyers

If you give value, you will get value back. Build Update Your Website

If you’re going to be marketing at all, first think about what your goals are. Begin marketing immediately, and tease your fans with project details leading up to its release.

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You’ve only read some of this guide.lock

The rest is only for members.

Encourage as many people as possible to like your fan page on Facebook. Run Contests Giveaways

Here are 23 quick fire music marketing tips that you can begin using right away. You’ll get more value out of them that way.

12. If you want something more indepth, be sure to get our free music marketing ebook newsletter.

1. Just remember to keep it legal, particularly if you’re going to be using social media. This is some of the best advice I can give you for marketing your music.

If you have a new project in the works, don’t wait around for its release date to start promoting it. Ask them how you could make their experience better. Do what you can to turn those hashtags into trending topics.

You’re in luck, because there are a lot of different ways to get your music out there, especially with the help of the internet.

8. Blog

7. Start building your email list right away, and give your fans plenty of opportunities to sign up for your list, both online and offline. Start Your Own Hashtag Campaigns

Book shows at regular intervals to share your latest and best songs with your fans. Promote Early, Promote Often

Blogging isn’t for everyone, but it is a great way to keep connected with your fans and to share what’s happening in your career. Find out how you can serve them on an individual basis. Then, make a plan for how you’re going to reach those goals. Your blog posts are great items to share on social media too. Then, use the built-in Insights to get a sense of who your target audience is; their location, gender, age range, and so on.

Already a member? Login below…

Epic list of 23 music marketing tips all musicians should know –

Tweet This.

Your website should be the center of your online marketing activities. Perform Live

23 tips for marketing your musicFlyers aren’t anything new, but they still work. Build Your Email List

P.S. Use social media to build your following. Put more effort into out-of-town shows than local shows. Distribution is about getting your music into different stores, outlets, and apps. Otherwise, move onto other promotional ideas.

4. If you can see yourself posting regularly, then give it a try. Remember To Give Value

Click here for access!

Epic list of 23 music marketing tips all musicians should know –

Tweet This.

13. If you don’t know where you’re going, don’t expect to wind up there on autopilot.

11. Keep your profiles updated, and talk to your fans and followers often.

10. Marketing is about everything you do to promote yourself and your music. Show your fans that you care about them. Want to learn how to do that? Then get our free music marketing ebook emailed directly to you! A fool proof guide on how to get people to listen to your music.

They are two different things. A distributed release still has to be promoted.

3. Make local shows special so that the people who support you in your hometown aren’t burned out.

23 Quick Fire Music Marketing TipsLooking for some quick ideas on how to market your music?

Important: Are you on Youtube? Then subscribe to my channel (opens in a new window) for all the latest video guides.

2. If possible, make your flyers something people will hold onto rather than something they’ll immediately throw away. They will keep doing business with you if they know, like and trust you!

6. Set Goals Make A Plan

5. Build it, and then remember to keep it updated too.

9. Remember though, none of what you’ve learned will matter if you don’t know how to get your music out there and make people WANT to hear it. Know Your Target Audience

Contests and giveaways can really drum up attention for your music. Know The Difference Between Marketing Distribution. Share Often On Social Media

Email lists are power. Use flyers to promote your shows

Exploring Polyamides: Kevlar and Nylon

Modern industrial processes generally use high heat and pressure to efficiently produce the polyamide. Nylon and Kevlar as “un-natural” results of laboratory toil and talent save lives, increase human pleasure/safety in games, make people look better, and quietly change the world one molecule at a time.

Sources Barrie, Alison, “Forget Kevlar! Liquid body armor hardens on impact,” FOX News, April 5, 2012. Caswell, Adam, “Other Uses of Kevlar,” ffden-2.phys.uaf.edu, 2003. Clark, Jim, “Polyamides,” chemguide.co.uk, 2004. Daintith, John, editor, A Dictionary of Chemistry, Third ed., Oxford University Press, 1996. Emsley, John, Molecules at an Exhibition, Oxford University Press, 1998. Le Couteur, Penny and Burreson, Jay, Napoleon’s Buttons: 17 Molecules That Changed History, New York: Jeremy P. Kevlar assists people to enjoy the sporting life in: laminates that coat racecar drivers’ survival compartments, tennis and badminton racquets, skis, running shoes, puncture-resistant kayaks and canoes. Using apidic acid (hexanedioic acid) and 1,6-diaminohexane, he made “nylon 6,6″ with a simple condensation reaction whose product brilliantly mimicked many of the properties of silk.

Kevlar Vests Have Saved Many LivesLess than a century ago, a lightweight material strong enough to stop a bullet would have fallen firmly into the realm of science fiction; and attempts at bypassing the silkworm to create manmade sheer-and-sexy stockings were depressingly mired in baggy cellulose-based fabrics. Kevlar’s strands are powerfully attracted to one another, forming tightly-packed sheets rather than the ordinary mangled mess familiar to polymer enthusiasts everywhere.. Kevlar will dissolve in pure sulfuric acid, but so do many materials. Kevlar is most important for its effectiveness as body armor and bombproof material and this is due to the super-strong polymer mesh’s absorption of energy from bullets and blasts.

Nylon and Kevlar truly exhibit the fun “Merlin the Magician” quality of polymer chemistry. Kevlar is usually not affected by solvents, shows no signs of weakness after immersion in boiling water or liquid hydrocarbons even after years of exposure. While nylon perhaps did not have exactly the same sheen as silk, it nonetheless turned out to be almost perfect for stockings since it fitted tightly to the leg, was relatively durable, and could be made available to the public at an affordable price. Kevlar has its artistic side, too, when employed in musical instrument components such as reeds and drum heads

Of course, despite its wartime successes, it can’t stop a bullet. Despite these negative reasons, Kevlar is well worth its cost.

Finally, in 1938, Harvard University organic chemist Wallace Carothers polymerized nylon for Du Pont. This substitution causes hydrochloric acid rather than water to be released when the amide bond forms.

The Many Uses of Nylon

Du Pont contributed greatly to the American World War II effort. Nylon proved useful for many military applications such as weather balloons, parachutes, ropes, tire cords, and mosquito netting. Both use not-so-amazing monomers and the same taken-for-granted amide bond found in all peptides or proteins to produce macromolecules that beat nature at her own game. Kevlar is used for mining conveyor belts, fire-resistant clothing, safety gloves, chemical hoses, tear-proof sails for boats, storm-resistant buildings, mooring ropes for offshore oil rigs, tankers, and even the Mars Pathfinder landing apparatus.

There are now two other types of nylon fibers: nylon 6, produced by the self-condensation of 6-aminohexanoic acid (the original monomer is caprolactam; its ring opens when it polymerizes); and nylon 6, 10, polymerized from 1,6-diaminohexane and decanedioic acid. Forty years ago, Kevlar was widely used in Formula 1 racing tires, but the aforementioned problems have led to it being phased out of this application to a certain extent. It finally and fittingly hit the market in 1982, exactly fifty years after the creation of the last bullet-impervious material (i.e., Superman’s chest – of course, just a jest! On a more serious note, the bullet-deflecting material polymethyl methacrylate was first synthesized in 1931 by German chemist Dr. The main drawback to Kevlar is its rather exorbitant price. Unfortunately, the polymer in collodion was actually nitrocellulose, so Chardonnet silk had a distressing tendency to burst into flame or explode, giving a whole new meaning to the phrase “a dress to die for.”

Currently, a lighter, thinner, more flexible version of body armor is being developed: 10 layers of Kevlar are combined with a Shear Thickening Liquid, then placed over 31 layers of untreated Kevlar. Kevlar also presents other dilemmas since it is difficult to paint, cut, or drill; exhibits poor compression strength; displays susceptibility to degradation/decomposition with prolonged exposure to ultraviolet light. The cellulose polymer produced in this fashion absorbed moisture, though; and saggy fake-silk stockings hardly qualified anybody for the best-dressed list.

Like nylon, natural silk possesses amide bonds, but is a true pleated-sheet protein with chains mostly composed of the amino acids serine, alanine, and glycine. The severe bruising and internal trauma resulting from gunshot impact will be reduced by this improvement; physical fatigue caused by heavy armor should also be cut considerably.

The Many Uses of Kevlar

Kevlar’s tensile strength makes it a superior and effective defensive device for the walls of panic rooms and aircraft engine compartments, vests, flak jackets, head gear and related equipment for soldiers and police officers. During the 1950s, it even became the first so-called engineering plastic and was convenient for constructing machine cogs and bearings.

The unusual benzene-ring-containing backbone of Kevlar and the hydrogen bonding between the nitrogen-containing group and the oxygen of the carbonyl groups on adjacent chains contribute to its tremendous structural regularity. Tarcher/Penguin, 2003. “Macrolab Experiment Making Nylon 6 and 6, 10,” USM Polymer Science Online Laboratory, 1998. “Making the Modern World: Polymer and intermolecular bonds: Kevlar,” The Science Museum, 2004. Sullivan, C.C., “Betting on Kevlar: tomorrow’s wonder material,” smartplanet.com, October 20, 2011. Winter, Ruth, A Consumer’s Dictionary of Cosmetic Ingredients, New York: Three Rivers Press, 2009.The phrase “polymer centuries” adapted from “polymer century,” which may be found at p. But then, what on earth ever could? Oh, yeah…

Kevlar: The Super-strong Aromatic Polyamide

Also made by Du Pont, Kevlar is the registered trademark of a specific type of aromatic polyamide copolymer often called an aramid. Kevlar does not become brittle at very low temperatures, resists flames and weathering, and is nicely flexible for a variety of uses. Otto Rohm, but did not reach the general public until some years later)

One hundred and twenty years later, London experimenters Charles Cross, Clayton Beadle, and Edward Bevan synthesized viscose silk by forcing high-viscosity liquid through a spinnaret. In the world of beauty, nylon yields good synthetic resins, thickens cosmetics and makes them opaque, lengthens eyelashes, and soaks up superfluous facial oil. Within one year of nylon’s birth, 64 million pairs of hosiery made from it hopped off the shelves.

Kevlar is five times as strong as steel, exceedingly lightweight; does not twist or tear and garments made from it are lightweight and do not burden the wearer. It took the trusty amide bond and some creative organic chemistry to solve the former problem with Kevlar and the latter with nylon.

The Birth and Development of Nylon: The Definitive Artificial Silk

The first artificial silk was made in the late 1870s by Count Hilaire de Chardonnet, who noticed he could pull long threads from a spilled photographic solution known as collodion. In contrast, Nazi Germany invested heavily in cellulose-based rayon fabrics.Rayon doesn’t provide much protection in the bitter cold and the uniforms made from this material may have contributed to Germany’s failures on the Russian front during harsh winter weather.

Kevlar is not limited to the above herculean tasks alone. Composed of para-phenylenediamine and terephthalic acid (or its corresponding acid chloride), Kevlar was discovered in 1965 by Stephanie Kwolek, but various synthesis problems delayed its debut. 150 of Hoffman, Roald and Torrence, Vivian, Chemistry Imagined: Reflections on Science, Smithsonian Institution Press, 1993.

Nylon is still used to make much more than just the pantyhose ubiquitously referred to as “nylons.” Various types of clothing, the inner structure of automobile tires, boat sails, upholstery, and carpets all owe a profound debt to Du Pont and Carothers’s very practical and useful polyamide. In the modern process there is substitution of more reactive dichlorides (such as hexanedioyl dichloride) for dicarboxylic acids. Humankind’s chemical advances have altered society’s perceptions and expectations

Asian Food Blogs to Bookmark

They deserve better.

If I were bookmarking my best blog picks for East Asia’s major cuisines, these are the ones I would choose.

Written by a Filipino expatriate in L.A., Burnt Lumpia has a sense of humor too, which makes it a delightful read.

japanesefoodreport.com I love this website! Japanese food can be intimidating to the home cook. But the photos are small and spare, and there are very few entries that dive deeper into the food culture.

www.japanesefoodreport.com

[Note: Two countries are conspicuous in their absence — China and Thailand. Nguyen peppers her site with all the best Vietnamese recipes along with appetizing photographs.

 www.deliciousasianfood.com

koreanfood.about.com

The site is full of big, bold and beautiful photographs. Can anyone point me in the right direction?

vietworldkitchen.com The kitchen of the title is that of Andrea Nguyen, a professional food writer based in Northern California. And it wasn’t always clear if I was still on the main site.

Ever get a hankering for some great Hokkien mee? Want to throw together the perfect shabu-shabu? Looking for beautiful photos of mouth-watering caldereta? If you answered yes to any of these questions — and even if you didn’t — you won’t want to overlook these great websites dedicated to the cuisines of East Asia.

Now I’d like to know what your favorite Asian food blogs are!

burntlumpia.typepad.com

 www.vietworldkitchen.com

Still, if you want true inspiration in Asian cuisine, Rasa Malaysia can get you there.

rasamalaysia.com The grand dame of Asian food blogs, Rasa Malaysia covers not just Malaysian food, but the cuisine of all East Asia. Koreans love Korean food. About.com’s section on Korean food does an adequate, if bare-bones, job of covering Korean cooking. I you can point them out, I would love to know!!]

Navigating around the site is a little confusing, and it’s difficult to find specific recipes. Never fear! Burnt Lumpia is here!

Korea is a boisterously foodie nation. Ms. Not necessarily daily posts, but often enough to at least let you know the author is still living.

This well-photographed website includes all the Pinoy favorites — adobo, ukoy, pancit and, of course, lumpia. But a great food blog needs three things: awesome recipes, excellent photos and, above all, regular posts. The food photography is unbelievably beautiful, and the recipes are easy to understand and well organized.

burntlumpia.typepad.com Good Filipino recipes can be hard to find in cyberspace. And their hearty, bold cooking is becoming more and more popular throughout Asia and North America. Asian cuisine is no exception. It also makes good use of instructional videos, with helpful stuff like “Sharpening Japanese Knives” or making “Mizutaki Hot Pot.”

You can find genuine Malay recipes here. Not just take-out stuff like kung pao chicken, but fun things like hairy gourd soup and pineapple prawn sambal. But the Japanese Food Report gives you basic, homestyle Japanese meals and lots of helpful tips on Japanese ingredients and cooking methods.

Navigating your way around the site is a little confusing and can be a bit of a pain. And in the end I couldn’t find all that much. I just couldn’t find any blogs out there that passed my muster. Even so, I have to recommend JFP as one of the best Japanese food blogs I’ve come across.. The photos sometimes poorly lit, but they do a fine job of illustrating what a dish should look like.

She also has a number of entries covering other aspects of Vietnamese cooking, including information on special ingredients and historical background.

Of course, there are thousands of food blogs out there covering all kinds of food. It’s possible I’ve overlooked some that are truly wonderful. Many recipes have instructive photos to guide you through each step.

www.rasamalaysia.com

deliciousasianfood.com This is a blog devoted to a mixture of Chinese and Malaysian recipes, along with a smattering of recipes from other countries in the region.

koreanfood.about.com/b/ Well, I looked. Too many times clicking a link popped open a new window